Jafar (Aladdin) = Hans Gruber (Die Hard)
He's the villain maintaining perfectly groomed facial hair while wreaking havoc on a city of innocent people. Add in an extremely low voice for good measure and he'll be the perfect match for the movie's mostly-shirtless hero.
Captain Hook (Peter Pan) = Ernst Blofeld (James Bond: You Only Live Twice)
This physically deformed bad guy tries to overcompensate by dressing in custom made suits, though his subconscious jealousy of the protagonist's charm & good looks has resulted in an obsession with feeding people to water-dwelling beasts.
Ursula (The Little Mermaid) = Boss Tweed (Gangs Of New York)
Once a member of the higher powers, this villain relies heavily on their influence over people with strong desires. People fear them but the real danger comes when they send their beady-eyed cohorts to attack after victims.
Evil Witch (Snow White) = Alex Forrest (Fatal Attraction)
Feared by all, this villain is dangerously beautiful. They've got violently jealous tendencies and don't particularly care for people shorter than 4 feet.
Hans (Frozen) = Bill (Kill Bill)
Specializing in manipulating the wrong women, this villain ends up getting exactly what they deserve. But their biggest crime? Their haircut.
Step Mother (Cinderella) = Auntie Entity (Mad Max Beyond Thunderdome)
This classy lady knows how to exploit people to get what she wants. She uses her high social status to harshly enforce the rules but in the end is outsmarted by a character who can't even afford new clothes.
Gaston (Beauty & The Beast) = Bane (Dark Knight Rises)
The first thing you'll notice about this bad guy is his crushing strength and size, but with all the flexing and accessorizing to hide embarrassing facial features, its obvious they care more about their appearance than anything else.
Cruella de Vil (101 Dalmatians) = The Joker (The Dark Knight)
This villain uses a combination of manic behavior and poor makeup skills to intimidate people. Their real weapon of terror though? Smelling like wet dog and cigarettes.
Scar (The Lion King) = Hitler (Inglourious Basterds)
Just the ABSOLUTE worst. (Apologies to Hitler for lumping him in with Scar.)